Product ID:POLYESTER RESIN DION FR 6604T
MSDS Date:01/01/1987
FSC:8040
NIIN:00F040722
MSDS Number: BXMHB

KOPPERS ROOFING SERVICES

436 7TH AVE
PITTSBURGH, PA 15219-5000
US

Emergency Phone: 412-227-2280/800-553-5631

Info Phone: 412-227-2280/800-556-7737

Cage: 0EGB7

KOPPERS ROOFING SERVICES

PITTSBURGH, PA 15219 US

Telephone: 412-227-2884

Cage: 0EGB7

STYRENE, (MONOMER) (SUSPECTED ANIMAL CARCINOGEN BY IARC,

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: 40-45%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

EPICHLOROHYDRIN, CHLOROMETHYLOXIRANE (ANIMAL CARCINOGEN BY

CAS: 106-89-8

RTECS: TX4900000

Fraction By Weight: 0.5%

OSHA PEL 5 PPM (SKIN) TWA

ACGIH TLV: 0.38 MG/CUM IC (A2)

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 0.5%

ACGIH TLV: 174 MG/CUM (A2)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION
(POSSIBLE SEVERE). ABSORPTION OF LIQUID MAY PRODUCE DAMAGE TO
INTERNAL ORGANS. INHALATION: IRRITATION OF RESPIRATORY TRACT
INCLUDING NOSE & THROAT, COMA & DEATH.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, TEARING, BLURRED VISION, CORNEAL
DAMAGE, HEADACHES, DIZZINESS, NAUSEA, WEAKNESS, COLLAPSE, COMA.
Medical Cond Aggravated by Exposure:PRE-EXISTING DISEASE IN/HISTORY OF
AILMENTS INVOLVING THE KIDNEY, LIVER, SKIN, RESPIRATORY SYSTEM MAY
BE > THAN NORMAL RISK OF DEVELOPING ADVERSE EFFECTS WHEN EXPOSED TO
THIS MATERIAL.

First Aid:EYES: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS.
SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH
AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: NO
SPECIFIC ANTIDOTE FOR EFFECTS FROM OVEREXPOSURE. TREATMENT SHOULD
BE DIRECTED AT CONTROL OF SYMPTOMS & CLINICAL CONDITION.

Flash Point Method:PMCC
Flash Point:85F
Lower Limits:1.1
Upper Limits:6.1
Extinguishing Media:USE CO2, DRY CHEMICAL/FOAM. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:WEAR COMPLETE PROTECTIVE EQUIPMENT, INCLUDING
FULL FACE MSHA/NIOSH APPROVED SCBA. USE WATER TO COOL
CONTAINER/STRUCTURE/PROTECT PERSONNEL. (SEE SUPP)
Unusual Fire/Explosion Hazard:VAPORS FORM FLAMMABLE/EXPLOSIVE MIXTURES
IN AIR. VAPORS ARE HEAVY, MAY TRAVEL TO IGNITION SOURCES. IF
POLYMERIZATION OCCURS EXPLOSIVE RUPTURING MAY OCCUR.(SUPP)

Spill Release Procedures:STOP W/OUT RISK. STAY UPWIND. SMALL: TAKE UP
W/SAND/NONCOMBUSTIBLE ABSORBENT MATERIAL. FLUSH W/WATER. LARGE:
DIKE FOR LATER DISPOSAL. CONTAIN RUNOFF FROM FIRE CONTROL &
DILUTION WATER.

Handling and Storage Precautions:DON'T WEAR CONTAMINATED CLOTHING. KEEP
IN CLOSED, LABELED CONTAINER W/IN COOL DRY VENTILATED AREA. PROTECT
FROM PHYSICAL DAMAGE. GROUND & BOND DRUMS.
Other Precautions:AVOID BREATHING OF VAPORS, MISTS/FUMES & CONTACT
W/SKIN/EYES. NOT FOR USE/STORAGE IN/AROUND THE HOME. DON'T USE
PRESSURE TO EMPTY DRUMS.

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE CONDTIONS.
Ventilation:NOT NORMALLY REQUIRED. LOCAL EXHAUST: ENCLOSED/CONFINED
SPACES.
Protective Gloves:POLYVINYL ALCOHOL/POLYETHYLENE
Eye Protection:INDUSTRIAL SAFETY GLASSES
Other Protective Equipment:USE SIDE SHIELDS/FACE SHIELD, CHEMICAL
GOGGLES W/FACE SHIELD/APRONS/JACKETS/PANTS/COVERALLS/BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DON'T WEAR CONTAMINATED CLOTHING. DISCARD CONTAMINATED
SHOES.
Supplemental Safety and Health
SPECIAL FIRE CONT'D: LARGE: BEST DONE AT A DISTANCE/PROTECTED LOCATION.
UNUSUAL FIRE CONT'D: STYRENE VAPORS ARE UNINHIBITED. POLYMERS MAY
FORM IN STORAGE TANK VENTS/FLAME ARRESTORS RESULTING IN VENT S
TOPPAGE/EXPLOSIVE RUPTURING.

Boiling Pt:B.P. Text:295F
Vapor Pres:4.5
Spec Gravity:1-1.4
pH:<7
Evaporation Rate & Reference:(ETHER =1): SLOWER
Solubility in Water:SLIGHT
Appearance and Odor:MORE VISCOUS THAN WATER. VISCOUS LIQUID W/STYRENE
ODOR.
Percent Volatiles by Volume:20-70

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ACIDS, CAUSTIC, METALLIC HALIDES, PEROXIDE
Stability Condition to Avoid:HEAT, OXIDIZING AGENTS, FREE RADICAL
CATALYSTS
Hazardous Decomposition Products:SMOKE, CO2, CO, HALOGENS & HALOGEN
BYPRODUCTS

Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. LIQUID POLYESTER RESIN WASTE HAVING A FLASH POINT
<140F IS A HAZARDOUS WASTE, HAVING IGNITABILITY D001. WASTE
RELEASED INTO ENVIRONMENT IN >100 LBS M UST BE REPORTED TO NATIONAL
RESPONSE CENTER.UN1866

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.